Bikes should be an integral part of transportation in the city. Instead, because of insensitive drivers and car doors, many travel by car to a more suitable location. Sort of negates the environmental benefits.
If you pedaled at 20 mph off the end of a truck that was traveling forward at 25 mph, you would be moving at 5mph in reverse. I would imagine it wouldn't be very good for the mechanics of the cycle, also very hard to control .